Sulfide-driven arsenic mobilization from arsenopyrite and black shale pyrite   总被引：1，自引：0，他引：1  

Wenyi Zhu  Nathan Yee  E. Danielle Rhine  John R. Reinfelder 《Geochimica et cosmochimica acta》2008,72(21):5243-5250

We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As−1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O₂), hypoxic (2% O₂, 98% N₂), and anoxic (5% H₂, 95% N₂) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (−1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black shale formations.  相似文献   

Seasonal warm-water refuge and sanctuary usage by the Florida manatee (Trichechus manatus latirostris) in Kings Bay,Citrus County,Florida     

Danielle C. Sattelberger  Joyce M. Kleen  Aarin-Conrad Allen  Richard O. Flamm 《地理信息系统科学与遥感》2017,54(1):1-19

The largest Florida manatee (Trichechus manatus latirostris) aggregation at a natural warm-water site occurs in Kings Bay, Crystal River, FL. In accordance with the Manatee Recovery Plan, manatee protection areas within Kings Bay have been created by the United States Fish and Wildlife Service (USFWS) and the State of Florida including a year-round refuge designation and seven Federal manatee sanctuaries during the winter manatee season (15 November–31 March). Over the last 30 years, an increase in manatee counts has been observed in Kings Bay which has prompted the need to review existing manatee protection measures. Aerial survey data collected between 1983 and 2012 were used to examine the seasonal change in manatee distribution within Kings Bay to assess the effectiveness of current sanctuary sizes and locations. Regression analysis suggested a significant change in manatee abundance among the winter seasons (p < 0.05). The average winter manatee counts increased by 4.81 animals per year over the 30-year period. Spatially explicit maps using geographic information system (GIS) analysis revealed a strong correlation between high manatee density and artesian springs in Kings Bay during the winter seasons. Highest abundances were identified at three locations: King Spring, Three Sisters Springs, and Magnolia Springs, which coincide with preexisting sanctuary designations. Additional coverage is advocated to support the overflow of manatees outside of sanctuary boundaries. As density patterns were not uniform across summer periods, a consideration of additional boat speed regulations is recommended.  相似文献   

Long-Term Trends of Nutrients and Phytoplankton in Chesapeake Bay     

L. W. HardingJr.  C. L. Gallegos  E. S. Perry  W. D. Miller  J. E. Adolf  M. E. Mallonee  H. W. Paerl 《Estuaries and Coasts》2016,39(3):664-681

Climate effects on hydrology impart high variability to water-quality properties, including nutrient loadings, concentrations, and phytoplankton biomass as chlorophyll-a (chl-a), in estuarine and coastal ecosystems. Resolving long-term trends of these properties requires that we distinguish climate effects from secular changes reflecting anthropogenic eutrophication. Here, we test the hypothesis that strong climatic contrasts leading to irregular dry and wet periods contribute significantly to interannual variability of mean annual values of water-quality properties using in situ data for Chesapeake Bay. Climate effects are quantified using annual freshwater discharge from the Susquehanna River together with a synoptic climatology for the Chesapeake Bay region based on predominant sea-level pressure patterns. Time series of water-quality properties are analyzed using historical (1945–1983) and recent (1984–2012) data for the bay adjusted for climate effects on hydrology. Contemporary monitoring by the Chesapeake Bay Program (CBP) provides data for a period since mid-1984 that is significantly impacted by anthropogenic eutrophication, while historical data back to 1945 serve as historical context for a period prior to severe impairments. The generalized additive model (GAM) and the generalized additive mixed model (GAMM) are developed for nutrient loadings and concentrations (total nitrogen—TN, nitrate?+?nitrate—NO₂?+?NO₃) at the Susquehanna River and water-quality properties in the bay proper, including dissolved nutrients (NO₂?+?NO₃, orthophosphate—PO₄), chl-a, diffuse light attenuation coefficient (K _D (PAR)), and chl-a/TN. Each statistical model consists of a sum of nonlinear functions to generate flow-adjusted time series and compute long-term trends accounting for climate effects on hydrology. We present results identifying successive periods of (1) eutrophication ca. 1945–1980 characterized by approximately doubled TN and NO₂?+?NO₃ loadings, leading to increased chl-a and associated ecosystem impairments, and (2) modest decreases of TN and NO₂?+?NO₃ loadings from 1981 to 2012, signaling a partial reversal of nutrient over-enrichment. Comparison of our findings with long-term trends of water-quality properties for a variety of estuarine and coastal ecosystems around the world reveals that trends for Chesapeake Bay are weaker than for other systems subject to strenuous management efforts, suggesting that more aggressive actions than those undertaken to date will be required to counter anthropogenic eutrophication of this valuable resource.  相似文献   

Reply to “Discussion of “The relation between dilatancy,effective stress and dispersive pressure in granular avalanches” by P. Bartelt and O. Buser (DOI: 10.1007/s11440-016-0463-7)” by Richard Iverson and David L. George (DOI: 10.1007/s11440-016-0502-4)     

Perry Bartelt  Othmar Buser 《Acta Geotechnica》2016,11(6):1469-1473

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PCA and SVM as geo-computational methods for geological mapping in the southern of Tunisia,using ASTER remote sensing data set     

Anis Gasmi  Cécile Gomez  Hédi Zouari  Antoine Masse  Danielle Ducrot 《Arabian Journal of Geosciences》2016,9(20):753

The purpose of this study was to examine the efficiency of Advanced Space Borne Thermal Emission and Reflection Radiometer (ASTER) data in the discrimination of geological formations and the generation of geological map in the northern margin of the Tunisian desert. The nine ASTER bands covering the visible (VIS), near-infrared (NIR) and short-wave infrared (SWIR) spectral regions (wavelength range of 400–2500 nm) have been treated and analyzed. As a first step of data processing, crosstalk correction, resampling, orthorectification, atmospheric correction, and radiometric normalization have been applied to the ASTER radiance data. Then, to decrease the redundancy information in highly correlated bands, the principal component analysis (PCA) has been applied on the nine ASTER bands. The results of PCA allow the validation and the rectification of the lithological boundaries already published on the geologic map, and gives a new information for identifying new lithological units corresponding to superficial formations previously undiscovered. The application of a supervised classification on the principal components image using a support vector machine (SVM) algorithm shows good correlation with the reference geologic map. The overall classification accuracy is 73 % and the kappa coefficient equals to 0.71. The processing of ASTER remote sensing data set by PCA and SVM can be employed as an effective tool for geological mapping in arid regions.  相似文献   

Eminent domain destroys a community: leveling East Arlington to make way for the Pentagon     

Nancy Perry 《Urban geography》2016,37(1):141-161

This study examines the eminent domain action in 1942 where the federal government took 411 acres of land, including an African American neighborhood, to construct the Pentagon building in Arlington County, Virginia. The Fifth Amendment of the U.S. Constitution acknowledges the right of the federal government to exercise eminent domain where needed for the common good, but requires that property owners be given just compensation. This study explores the issue of compensation: what the residents lost when they were forced to move, how that loss was compensated, and whether the compensation was “just.” The study data include interviews with former residents of the neighborhood, oral histories, land records, census data, photographs, and newspaper articles. The study concludes that the federal government compensated the residents for land and buildings, but was unable to compensate for a lost community. For many residents, that community is mourned even 72 years later.  相似文献   

Detection of rovibrationally excited H2 formed through the heterogeneous recombination of H atoms on a cold HOPG surface     

J.S.A. Perry  S.D. Price 《Astrophysics and Space Science》2003,285(3-4):769-776

This paper reports results from an experiment designed to measure the nascent rovibrational population of H₂ molecules that have formed through the heterogeneous recombination of H atoms on the surface of cosmic dust analogues under conditions approaching those of the interstellar medium (ISM). H₂ that has formed on a highly oriented pyrolytic graphite (HOPG) surface has been detected, using laser induced resonance-enhanced multi-photon ionization (REMPI), in the v = 1 (J= 0–3) rovibrational states at surface temperatures of 30 K and 50 K. These excited product molecules display rotational temperatures significantly higher than the target surface temperature. These first results suggest that a considerable proportion of the binding energy released on formation of the H₂ is deposited in the surface, in addition to internal excitation of the product molecules. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Improved three-dimensional mapping of the electron density distribution of the solar corona     

R. Michael Perry  Martin D. Altschuler 《Solar physics》1973,28(2):435-456

Three-dimensional maps of the distribution of coronal electron density can now be computed with two radial functions in the series expansion for the density (rather than with only one radial function as shown in our previous paper). With the improved maps we can determine the topological variation of the electron density with radial distance, and thus can (1) distinguish coronal condensations from coronal streamers, (2) trace the structure of a streamer as a function of height, and (3) determine the non-radial orientation of a streamer. We summarize the previous work in concise mathematical notation, show examples of the improved maps derived from two radial functions, and discuss in detail the expectations and limitations of the method. Of great utility are computer-simulated pictures showing the solar corona as it would appear if veiwed from above the north (or south) pole.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

Venture Capital in New Zealand     

Martin Perry 《New Zealand geographer》1988,44(1):2-7

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Book reviews     

Perry  John S.  Wigley  T. M. L. 《Climatic change》1981,3(4):453-457

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